Some physical properties of pure teg are given in the. Glycol dehydration is a liquid desiccant system for the removal of water from natural gas and natural gas liquids ngl. Water can collect in pipelines and increase the pressure drop andor cause slug flow. Pdf processing of natural gas sweeting, dehydration. Liquid water and hydrate formation will have an extensive impact on safety and operational reliability. Gas mexico congress gmc15 161 capex and opex considerations for gas dehydration technologies joeri olijhoek, frames gas treatment. Frozen control valves or plugged orifices can cause a complete shutdown.
Scribd is the worlds largest social reading and publishing site. Poor dehydration requires further, more detailed investigation dew points below spec. When i read several literatures related to natural gas dehydration, the. Thermodynamic simulation of gas dehydration is difficult due to the interaction be. Teg glycol dehydration when taken from the wellhead, natural gas is partially saturated with water. Glycol dehydration, page 4 natural gas is transported to high demand areas via an elaborate network of pipelines, and is sometimes stored when it is not required.
Farman abstract the purpose of this research is to study the dehydration process of natural gas by adsorption using molecular sieve as it is in the north gas. Natural gas dehydration is essential in many processes due to the presence of humidity in varying concentrations. This step will be explained in detail in the liquefaction section of this report. The glycol dehydration process is an example of a process that provides absorption dehydration, and in the process, a liquid desiccant provides the means to absorb water from the gas stream. Optimization of natural gas dehydration using triethylene glycol was carried out using aspen hysys process software and regression analysis.
If the composition of co2 exceeded that limit it would freeze in the liquefaction process pipelines. Glycol dehydration most common to produce water contents down to. Natural gas in transit to market should be dehydrated to a controlled water content to avoid hydrates, as well to minimize the corrosion problems. Produced gas is saturated with water, which must be removed for gas processing and transmission. Natural gas dehydration unit dehydration of natural gas. Modelling of natural gas sweetening and dehydration processes. This criteria was developed decades ago and is likely based on the mckettaweheb moisture prediction chart to avoid the formation of hydrates and an aqueous phase during the transmission of natural gas. This work shows a study of natural gas dehydration using 3a molecular sieve as a type of solid desiccant materials, the scope of this work was to build up a pilot scale unit for a natural gas. Gas hydrates are crystals of natural gas and water which can appear fare above. The technology of natural gas dehydration with ionic liquids ils as a promising method was proposed and systematically investigated in this work. Glycol dehydration troubleshooting guide oil and gas. Low temperature separation unit lts at the wellhead, natural gases are saturated with water.
Typically, natural gas dehydration criteria is stated as a water content value. First, co2 and h2s removal stage which is constructed to assure that co2 would not exceed 50 ppm in the natural gas feed. Dry glycol flows down the tower from the top, from tray to tray or through packing material. At the rig, natural gases are nearly always saturated with water. Capex and opex considerations for gas dehydration technologies. Engineering design guidelines gas dehydration rev01web. Natural gas facilities are designed to handle water removal from the gas stream to meet pipeline specification of water content in the processed gas stream. The glycol dehydration unit is a reliable, efficient system for removing water from natural gas well streams in order to meet typical pipeline and process. It can increase pressure drop in the line and often leads to corrosion problems. Natural gas is available in two phases hydrates and gas. Gas dehydration is widely used in natural gas treatment plant as a common process, because water and hydrocarbon can form hydrates ice formation which may block valve and pipelines.
Liquid water can collect in pipelines and increase the pressure drop and cause slug flow. It is the most common and economical means of water removal from these streams. Betsy casada sunday, july 23, 2017 the presence of waterwater vapor in natural gas causes hydrates solid, icelike crystals of hydrocarbons and water that form under high pressure in well streams with a low temperature which in turn cause freezing and blocking of pipelines, valves and other equipment, effectively shutting. Gas dehydration field manual defines the various methods of gas dehydration and discusses the differences between adsorption and absorption. The specific focus of the report is gas dehydration and the processes involved. Index terms natural gas hydrates, hydrate structure, gas dehydration, cooling load optimization introduction. Delta gas plant dehydration process using the hysys simulator. With all units optimally specified during the process, the lean teg inflow rate was varied with the water content in the dry gas product stream of. Free water can freeze and form solid hydrates and reduce the gas flow or plug the line. Bastiaan leeuw, frames gas treatment this paper has been selected for presentation andor publication in the proceedings for the 2015 gas mexico congress. Natural gas is a mixture of gases, rich in hydrocarbons formed from the buried fossils and plants under high pressure and temperature for thousands of years.
Absorption is usually performed by using teg triethylene. Although dehydration historically has been a fairly inexpensive step in the upgrading of natural gas to pipeline quality, costs are increasing. The dehydration process is simplewet gas contacts dry glycol, and the glycol absorbs water from the gas. Natural gas processing ppt natural gas processing natural gas. When watersaturated natural gas flows in a pipeline the following problems can occur. The condensation method is therefore usually applied for simultaneous dehydration and recovery of natural gas liquids. This paper compares three methods for natural gas dehydration that are widely applied in industry. Absorption proceeds at low temperatures and the absorbed water is boiled out from teg during regeneration in a reboiler at high temperatures. Treated gas from the agru is fed to the gas dehydration unit to avoid any potential problems resulting from water vapor condensation and accumulation in the pipelines i. A third safety step is taken in the liquefaction process where molecules of water, which accompany the natural gas in the feed, are condensed and flashed in the stage of natural gas precooling.
Optimization of natural gas dehydration using triethylene. With the use of hysys software, natural gas dehydration plant was designed. Jan 11, 2017 the technology of natural gas dehydration with ionic liquids ils as a promising method was proposed and systematically investigated in this work. Tegi t i b ti tteg is most common in absorption systems meg is most common in glycol injection systems. Introduction natural gas is a combustible mixture of hydrocarbon gases and a vital component of the worlds supply of energy. Troubleshooting a glycol dehydration system is a bit more nuanced but the authors quote pretty much forms the basis for the process.
In natural gas systems, removing water vapor reduces pipeline corrosion and eliminates line blockage caused by hydrate formation. Water also can cause corrosion in the presence of acid gas component in natural gas. It is one of the cleanest, safest and most useful of all energy. Several natural gas dehydration methods and range of application. Several natural gas dehydration methods and range of. The il emimtf2n was screened out as an appropriate absorbent from 252 il candidates for the natural gas dehydration process by means of the cosmors model. To perform a good troubleshoot on glycol dehydration equipment, you must know what the system is designed for and how the current conditions compare to that design. Dehydration of natural gas iit kharagpur july 2018. Two subsea natural gas treatment processes, namely natural gas dehydration and acid gas removal, are discussed in details with respect to the advantages and challenges in the implementation of. Pdf dehydration of natural gas is needed to remove the water that is associated with natural gases in vapor form. Oct 14, 2018 comparison of natural gas dehydration methods 1,2 general overview of applicability of each dehydration method is shown in figure below.
Natural gas dehydration unit is a facility used to remove water in gas stream. Fuel gas, page 5 pipeline quality natural gas is ready to be delivered to consumers for use in homes and businesses. Pdf a study of the dehydration process of natural gas in iraqi. Liquid desiccants have found an extremely wide use for the dehydration of natural gas, and the bulk of this discussion will be centered upon glycols as utilized in gas dehydration. Water vapor increases natural gases corrosivity, especially when acid gases are present. Booster station, page 5 natural gas accounts for 25% of energy usage.
Glycol dehydration systems are not only efficient at removing water from a natural gas stream, they also remove benzene, toluene, ethylbenzene, and xylene btex as well as other volatile organic compounds vocs. There are at least three commercial methods of natural gas dehydration, which are absorption, adsorption, and condensation. Glycol dehydration process an overview sciencedirect topics. Comparison of three methods for natural gas dehydration. General selection chart of natural gas dehydration method 1, with modification bonus. Process trace moisture analyzer for natural gas glycol. Produced gas is saturated with water, which must be removed for gas transmission glycol dehydrators are the mostcommon equipment to remove water from gas 36,000 dehydration systems in natural gas production, gathering, and boosting most use triethylene glycol teg glycol dehydrators create emissions methane, vocs, haps from reboiler vent. There are several methods of dehydrating natural gas, including absorption, adsorption, and direct cooling of the wet gas. The raw natural gas extracted from production wells contains many impurities that must be removed in order to achieve the speci cations of the liqui ed natural gas lng andor the pipeline gas. Glycol dehydrators, part of natural gas dehydration systems, remove water vapor from gas streams to prevent the formulation of hydrates and corrosion in pipelines.
Pdf on oct 31, 2012, michal netusil and others published natural gas dehydration find, read and cite all the research you need on. This stage is directed more to co2 removal since the bolivian natural gas contains no sulfur in. Some physical properties of pure teg are given in the following text. In order to achieve such speci cations, the raw gas must pass through a series of puri cation steps, which compose the socalled natural gas chain. Contents vii disadvantages 43 plunger pumps 43 advantages 43 disadvantages 43 comparisonofhydrate prevention methods 43 overview 43 heaters 44 chemical injection 44 downholeregulators 44 summaryof hydrate prevention methods 45 hydrateinhibition 45 hammerschmidt equation 45 determinationoftotal inhibitor required 47 procedurefor determining. When watersaturated natural gas flows in a pipeline. Frost on exterior of tower gas temps below 30 degrees farenheit clogge trays or packing in tower unusually loud noise partially plugged trays or packing high pressure or high velocity gas tower may be undersized dew points dew points above spec. Filters for the natural gas industry parker hannifin. Glycols typically seen in industry include triethylene glycol teg, diethylene glycol deg, ethylene glycol meg, and tetraethylene glycol treg. Introduction water vapor is the most common undesirable impurity in gas streams. Lng dehydrationdrying of natural gas absorption and refrigeration with hydrate inhibition is the most common dehydration process used to meet pipeline sales specifications. Natural gas is an important source of primary energy that, under normal production conditions, is saturated with water vapor.
This report is therefore introduced with a brief description of the danish off. Glycols are extremely effective for natural gas heatexchangers and natural gas dehydration due to their thermal and chemical stability, availability at moderate costs, continuous usefulness and ease of. Exterrans unit provides you with reliability, efficiency and flexibility in a single package and a wide range of options to meet your needs. The natural gas industry has recognized that dehydration is. Absorption is the most widely used industrial natural gas dehydration. Natural gas liquids and condensed higher hydrocarbons can also be recovered from ng by cooling.
The axes are water content in the wet gas, in lbmmscf and dry gas dew point, in f. Natural gas dehydration serving the arklatex, oklahoma, new mexico and all of the lower forty eight states. Gas dehydration 6 aalborg university esbjerg 1 introduction the offset for this report is the offshore oil and gas production in the danish sector in the north sea. This research is considered as an introduction for designing a natural gas processing plant it concerns with natural gas processing systems sweeting, dehydration, fractionation, liquefaction and recovery as an example for natural gas processing. Reasons for gas dehydration field operations prevent hydrate formation minimize corrosion need to dry gas to dew point below lowest operating temperature plant operations need 4 to 7 lbmmscf 85 to 150 ppmv in pipeline glycol dehydration most common to produce water contents down to 10 ppmv need to have less than 1 ppmv h 2. Natural gas dehydration 5 temperatures and the absorbed water is boiled out from teg during regeneration in a reboiler at high temperatures. Natural gas dehydration lessons learned from the natural gas star program conocophillips the colorado oil and gas association, and the independent petroleum association of mountain states producers technology transfer workshop durango, colorado september, 2007 epa.
In the transmission of natural gas further condensation of water is problematic. Troubleshooting a glycol dehydration system oil and gas. Solutionstm glycol dehydration unit is a complete water vapor removal system used on natural gas well streams to meet typical pipeline and process specifications. Water can freeze andor form solid hydrates, consequently reducing the gas flow or plugging the line. Schlumberger glycol dehydration processes remove water vapor from natural gas, which. Produced gas is saturated with water, which must be removed for gas transmission. Natural gas phase behavior the natural gas phase behavior is a plot of pressure vs temperature thatdetermines whether the natural gas stream at a given pressure andtemperature consists of a single gas phase or two phases. Ng can be advantageously cooled using the joulethompson effect jt effect. The phase behavior for natural gas with a given composition is typicallydisplayed on a phase diagram, an.
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